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TEM and EELS microanalysis of pc-Si thin film solar cells deposited by means of HW CVD

M. Stögera,*, P. Schattschneidera , V. Schlosserb, R. Schneiderc, H. Kirmsec, W. Neumannc

aInstitute of Applied and Technical Physics. Vienna University of Technology. Wiedner Hauptstr. 8-10, A-1040 Wien. Austria
bInstitute for Material Physics. University of Vienna. Austria
cInstitute of Physics. Humboldt University of Berlin, Chair of Crystallography. Germany


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Abstract
A p-i-n doped pc-silicon thin film grown by means of hot wire chemical vapour deposition (HW CVD) on a zinc oxide film has been investigated by transmission electron microscopy (TEM) and electron energy loss spectroscopy (EELS). The structure of both layers, the ZnO substrate layer as much as the silicon thin film and the chemical composition at the interface were the subjects of our investigations. We found that a file of pure silicon with a thickness of about 5 nm covers the substrate surface. A plausible model for getting information on the wavyness of the interface ZnO/pc-Si and the thickness of this pure Si-layer was developed.
Keywords:
Thin film; Transmission electron microscopy; Electron energy loss spectroscopy

*Corresponding author. Tel.: +43-1-58801-13720; fax: +43-1-58801-13798.
E-mail address: M. Stöger


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