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INVESTIGATIONS OF EVAPORATED FRONT CONTACTS ALONG THE GRAIN BOUNDARIES OF MULTICRYSTALLINE SILICON SOLAR CELLS

V. Schlosser1, R. Ebner2, W. Markowitsch1, P. Bajons1, G. Klinger3, A. A. El-Amin1, J. Summhammer2

  1. Institut für Materialphysik der Universität Wien, A-1090 Wien, Strudlhofgasse 4, Austria.

  2. Atominstitut der Österreichischen Universitäten, A-1020 Wien, Stadionallee 2, Austria.

  3. Institut für Meteorologie und Geophysik der Universität Wien, A-1090 Wien, Althanstraße 14, Austria.


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ABSTRACT
A series of sets of multicrystalline silicon solar cells have been prepared. One cell of each set was equipped with a front contact grid along the grain boundaries. A second cell was equipped with the same grid but rotated by 90 degrees and onto the third cell a geometrical standard grid was applied. The grids were either prepared by plotting silver ink lines and subsequent burn in or by photolithographically structured Ni/Ag layers deposited by evaporation or a galvanic process. No passivation or protection against reflection losses were applied. A statistical evaluation of the solar cell parameters for two illumination intensities in a temperature range between 295 K and 330 K was done. At room temperature the gain of maximum output power for cells with the grid on the grain boundaries for high and low light intensities was 1.17 and 1.15, respectively, compared with cells having a standard grid. The average linear temperature coefficient for the power output was determined to be -0.80 %K-1 for cells with a grain boundary grid and -0.74 %K-1 for cells with a standard grid. For one cell prepared by the photolithographic method a maximum power output of more than 10 mWcm-2 was observed under 1 kWm-2 irradiation at ambient temperature.
Keywords:
Silicon - 1: Multi-Crystalline - 2: Contact - 3.

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